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monolithic silica

Advances in monolithic silica columns for high

2017年9月3日  This review attempts to give an overview of three different types of monolithic columns, i.e. silica-based, polymer-based, and hybrid monolithic

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Monolithic Silica Columns for HPLC, Micro-HPLC, and CEC

2000年1月31日  Two types of monolithic silica columns derivatized to form an ODS phase, one prepared in a fused silica capillary (SR-FS) and the other prepared in a mold and clad with an

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Advancements in the preparation and application of monolithic silica ...

2021年3月1日  Silica monolithic column has been introduced and fabricated through sol-gel method. Several types of monolith surface functionalization and endcapping are presented.

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Preparation of monolithic silica HPLC columns with truss

2024年10月26日  By introducing weakly acidic reaction conditions and appropriate post-gelation aging process of wet silica gels, it became finally possible to fabricate monolithic silica with

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Recent Progress in Monolithic Silica Columns for High-Speed

This review looks at how the size range of monolithic silica columns has been expanded, how high-efficiency monolithic silica columns have been realized, and how various methods of

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Monolithic silica columns for high-efficiency chromatographic ...

2002年8月2日  Monolithic silica columns prepared from tetraalkoxysilane by a sol–gel method showed high efficiency and high permeability on the basis of the small-sized silica skeletons,

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Monolithic Silica SnG Inc.

Monolithic silica has excellent thermal stability, mechanical strength and chemical stability because of its unique mesh-like skeleton. Monolithic silica is pure silica gel and withstands high temperatures exceeding 800 ℃. Also, it will not break

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Monolithic Silica with Bimodal Pore Structure

Chromolith ® HPLC and UHPLC columns are made from monolithic silica with a bimodal pore structure using sol-gel technology. Mesopores and macropores are formed within the monolithic silica. The column is no longer packed with small

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Properties of Monolithic Silica Columns for HPLC

2006年4月14日  Monolithic silica columns and their use in high peak-capacity HPLC separations are reviewed. Monolithic silica columns can potentially provide higher overall performance

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Chromatographic Properties of Minimal Aspect Ratio Monolithic Silica ...

2021年3月12日  We report on a study wherein we synthesized TMOS-based silica monolithic skeletons in capillaries with an i.d. of 5 and 10 μm to produce skeleton structures with very low

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Advancements in the preparation and application of monolithic silica ...

2021年3月1日  Silica monolithic columns were first proposed by Kazuki Nakanishi's group, where the bi-continuous pore structure silica gels were prepared through the sol-gel phase transformation. The procedure was complicated and sensitive [43]. Generally, the throughpore sizes formed are mainly controlled to be within the range of 1.5–8 μm during ...

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Properties of Monolithic Silica Columns for HPLC

2006年4月14日  Monolithic silica columns and their use in high peak-capacity HPLC separations are reviewed. Monolithic silica columns can potentially provide higher overall performance than particle-packed columns based on the variable external porosity and variable through-pore size/skeleton size ratios. The high permeability of monolithic silica columns resulting from the

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Recent Progress in Monolithic Silica Columns for High-Speed

Monolithic silica columns have greater (through-pore size)/(skeleton size) ratios than particulate columns and fixed support structures in a column for chemical modification, resulting in high-efficiency columns and stationary phases. This review looks at how the size range of monolithic silica columns has been expanded, how high-efficiency monolithic silica columns have been

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A new route to aerogels: Monolithic silica cryogels

2012年2月1日  We have explored several routes to synthesize monolithic silica cryogels. We highlight two routes to monoliths with similarities to the corresponding aerogels. Low freezing temperatures and fast cooling rates favor monolithicity. Uniform networks and a high degree of 3-D cross-linking correlate with monolithicity. Compared to aerogels, cryogels exhibit larger

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Advancements in the preparation and application of monolithic silica ...

2021年3月1日  A column with high resolution and efficiency is needed in order to achieve good separation. Column resolution and efficiency can be improved by considering factors such as the length of the column, internal diameter of the column, linear velocity (u), particle size, particle pore size, type of particles and the particle packing uniformity.Column resolution (R s) is affected by

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Monolithic silica aerogel in superinsulating glazings

1998年10月1日  France submitted a monolithic silica aerogel (carbogel) obtained by supercritical drying of CO 2, previously substituted to alcohol, referred to as FRA1. Norway submitted a monolithic xerogel sample produced by atmospheric pressure drying, referred to as NOR1.

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Onyx Monolithic High Speed HPLC Columns

Finish First with Monolithic Silica HPLC Columns. Monolithic columns are characterized by their unique structure, which consists of a continuous, porous monolithic material, typically made from silica or organic polymers. Onyx is a

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Preparation of monolithic silica columns for high

2008年5月16日  Monolithic silica columns are prepared by a sol–gel process. The chemical transition of an alkoxysilane solution to silica gel is generally caused by two kinds of reactions; hydrolysis and polycondensation, starting from Si(OR) 4 to form Si O Si bonds in silica oligomers and polymers. In the sol–gel process, reaction conditions are selected so that the formation of

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One-pot synthesis of monolithic silica-cellulose aerogel applying

2021年7月26日  The monolithic silica-cellulose aerogel can be synthesized from low modulus (1.5) silicate sol-gel process. The embedded CO 2 emission of this new aerogel is significantly reduced, reflected by the obviously lower footprint of olivine sodium silicate compared to commercial water glass, namely 2.481 tCO 2 /t and 5.517 tCO 2 /t, respectively.

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Monolithic Silica Capillary Columns with Improved Retention

2018年10月2日  A strategy for the preparation of silica-based monolithic capillary columns (150 × 0.1 mm) with high selectivity to amino acids is presented. The zwitterionic columns were prepared by coating the silica monolith with [2-(methacryloyloxy)ethyl]-dimethyl-(3-sulfopropyl)-ammonium hydroxide via 3-(trimethoxysilyl)propyl methacrylate. The columns were evaluated under

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A New Generation of Silica-Based Monoliths HPLC Columns

2012年4月1日  Preparation of Silica-Based Monolithic HPLC Columns. Silica-based monolithic columns are prepared according to a sol-gel process utilizing tetramethoxysilane (TMOS) as a silica precursor and polyethylene oxide (PEO) as a pore-forming agent (19). The two components TMOS and PEO are dissolved under slightly acidic conditions and the resulting ...

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革新的分離剤~シリカモノリス~ オリジナル技術

シリカモノリスは、連続した多孔質を有するシリカゲルであり、大きな比表面積が特徴です。 低圧での通液を可能とする分離用カラムや吸着剤など、目的の分析アプリケーションに最適化できます。

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Monolithic silica columns with various skeleton sizes and

2002年6月28日  Monolithic silica columns prepared in a fused-silica capillary in the presence of urea from TMOS or from a mixture of TMOS and MTMS were evaluated in HPLC. Reduction in through-pore size and skeleton size resulted in the increase of column efficiency at the expense of permeability. The monolithic silica columns, however, showed higher ...

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Antibody-coupled monolithic silica microtips for ...

2017年1月31日  Here we constructed anti-CD9 antibody-coupled highly porous monolithic silica microtips which allowed automated rapid and reproducible exosome extraction from multiple clinical samples. We applied these tips to explore lung cancer biomarker proteins on exosomes by analyzing 46 serum samples.

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Development of hydrophobic and optically

2016年10月26日  In the present paper, highly transparent, monolithic and hydrophobic silica aerogel monoliths were prepared by using tetraethoxysilane (TEOS) as precursor and methyltriethoxysilane (MTES) as co-precursor with

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Formation of monolithic silica gel microhoneycombs (SMHs ...

2017年1月31日  Monolithic silica gel microhoneycombs, which have an array of straight macropores within their structure and developed micro/mesopores inside their walls, were prepared using pseudosteady state growth of ice crystals which occurs during the ...

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HPLC Column Monolith Phenomenex Onyx

Finish First with Monolithic HPLC Columns Monolithic silica-based HPLC columns that are designed for high-throughput analysis and the direct injection of dirty or viscous samples. Reduce run times with extremely high flow rates (up to 9 mL/min) “Dilute-and ...

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Optimization of monolithic silica aerogel insulants

1992年9月1日  Optimization of monolithic silica aerogel insulants Optimisation des silica-aerosols monolithes isolants Optimierung von wärmedämmungen aus infrarot-getrübten aerogelen ru] ... Finally, it should be noted that for the nanoporous silica aerogel insulation material, there are still some key issues that need to be investigated to get deep ...

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Antibody-coupled monolithic silica microtips for highthroughput ...

2014年8月29日  Here we constructed anti-CD9 antibody-coupled highly porous monolithic silica microtips which allowed automated rapid and reproducible exosome extraction from multiple clinical samples. We applied ...

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Preparation of monolithic silica-based aerogels with high

2018年8月1日  A monolithic silica-based aerogels were successfully synthesized via a sol-gel process using tetraethoxysilane and inexpensive inorganic aluminium salt Al(H 2 O) 9 (NO 3) 3 as precursors. The gels were dried at ambient pressure and the molar ratio of Al/Si was varied from 0

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