2017年9月3日 This review attempts to give an overview of three different types of monolithic columns, i.e. silica-based, polymer-based, and hybrid monolithic
خبير الاتصال2000年1月31日 Two types of monolithic silica columns derivatized to form an ODS phase, one prepared in a fused silica capillary (SR-FS) and the other prepared in a mold and clad with an
خبير الاتصال2021年3月1日 Silica monolithic column has been introduced and fabricated through sol-gel method. Several types of monolith surface functionalization and endcapping are presented.
خبير الاتصال2024年10月26日 By introducing weakly acidic reaction conditions and appropriate post-gelation aging process of wet silica gels, it became finally possible to fabricate monolithic silica with
خبير الاتصالThis review looks at how the size range of monolithic silica columns has been expanded, how high-efficiency monolithic silica columns have been realized, and how various methods of
خبير الاتصال2002年8月2日 Monolithic silica columns prepared from tetraalkoxysilane by a sol–gel method showed high efficiency and high permeability on the basis of the small-sized silica skeletons,
خبير الاتصالMonolithic silica has excellent thermal stability, mechanical strength and chemical stability because of its unique mesh-like skeleton. Monolithic silica is pure silica gel and withstands high temperatures exceeding 800 ℃. Also, it will not break
خبير الاتصالChromolith ® HPLC and UHPLC columns are made from monolithic silica with a bimodal pore structure using sol-gel technology. Mesopores and macropores are formed within the monolithic silica. The column is no longer packed with small
خبير الاتصال2006年4月14日 Monolithic silica columns and their use in high peak-capacity HPLC separations are reviewed. Monolithic silica columns can potentially provide higher overall performance
خبير الاتصال2021年3月12日 We report on a study wherein we synthesized TMOS-based silica monolithic skeletons in capillaries with an i.d. of 5 and 10 μm to produce skeleton structures with very low
خبير الاتصال2021年3月1日 Silica monolithic columns were first proposed by Kazuki Nakanishi's group, where the bi-continuous pore structure silica gels were prepared through the sol-gel phase transformation. The procedure was complicated and sensitive [43]. Generally, the throughpore sizes formed are mainly controlled to be within the range of 1.5–8 μm during ...
خبير الاتصال2006年4月14日 Monolithic silica columns and their use in high peak-capacity HPLC separations are reviewed. Monolithic silica columns can potentially provide higher overall performance than particle-packed columns based on the variable external porosity and variable through-pore size/skeleton size ratios. The high permeability of monolithic silica columns resulting from the
خبير الاتصالMonolithic silica columns have greater (through-pore size)/(skeleton size) ratios than particulate columns and fixed support structures in a column for chemical modification, resulting in high-efficiency columns and stationary phases. This review looks at how the size range of monolithic silica columns has been expanded, how high-efficiency monolithic silica columns have been
خبير الاتصال2012年2月1日 We have explored several routes to synthesize monolithic silica cryogels. We highlight two routes to monoliths with similarities to the corresponding aerogels. Low freezing temperatures and fast cooling rates favor monolithicity. Uniform networks and a high degree of 3-D cross-linking correlate with monolithicity. Compared to aerogels, cryogels exhibit larger
خبير الاتصال2021年3月1日 A column with high resolution and efficiency is needed in order to achieve good separation. Column resolution and efficiency can be improved by considering factors such as the length of the column, internal diameter of the column, linear velocity (u), particle size, particle pore size, type of particles and the particle packing uniformity.Column resolution (R s) is affected by
خبير الاتصال1998年10月1日 France submitted a monolithic silica aerogel (carbogel) obtained by supercritical drying of CO 2, previously substituted to alcohol, referred to as FRA1. Norway submitted a monolithic xerogel sample produced by atmospheric pressure drying, referred to as NOR1.
خبير الاتصالFinish First with Monolithic Silica HPLC Columns. Monolithic columns are characterized by their unique structure, which consists of a continuous, porous monolithic material, typically made from silica or organic polymers. Onyx is a
خبير الاتصال2008年5月16日 Monolithic silica columns are prepared by a sol–gel process. The chemical transition of an alkoxysilane solution to silica gel is generally caused by two kinds of reactions; hydrolysis and polycondensation, starting from Si(OR) 4 to form Si O Si bonds in silica oligomers and polymers. In the sol–gel process, reaction conditions are selected so that the formation of
خبير الاتصال2021年7月26日 The monolithic silica-cellulose aerogel can be synthesized from low modulus (1.5) silicate sol-gel process. The embedded CO 2 emission of this new aerogel is significantly reduced, reflected by the obviously lower footprint of olivine sodium silicate compared to commercial water glass, namely 2.481 tCO 2 /t and 5.517 tCO 2 /t, respectively.
خبير الاتصال2018年10月2日 A strategy for the preparation of silica-based monolithic capillary columns (150 × 0.1 mm) with high selectivity to amino acids is presented. The zwitterionic columns were prepared by coating the silica monolith with [2-(methacryloyloxy)ethyl]-dimethyl-(3-sulfopropyl)-ammonium hydroxide via 3-(trimethoxysilyl)propyl methacrylate. The columns were evaluated under
خبير الاتصال2012年4月1日 Preparation of Silica-Based Monolithic HPLC Columns. Silica-based monolithic columns are prepared according to a sol-gel process utilizing tetramethoxysilane (TMOS) as a silica precursor and polyethylene oxide (PEO) as a pore-forming agent (19). The two components TMOS and PEO are dissolved under slightly acidic conditions and the resulting ...
خبير الاتصالシリカモノリスは、連続した多孔質を有するシリカゲルであり、大きな比表面積が特徴です。 低圧での通液を可能とする分離用カラムや吸着剤など、目的の分析アプリケーションに最適化できます。
خبير الاتصال2002年6月28日 Monolithic silica columns prepared in a fused-silica capillary in the presence of urea from TMOS or from a mixture of TMOS and MTMS were evaluated in HPLC. Reduction in through-pore size and skeleton size resulted in the increase of column efficiency at the expense of permeability. The monolithic silica columns, however, showed higher ...
خبير الاتصال2017年1月31日 Here we constructed anti-CD9 antibody-coupled highly porous monolithic silica microtips which allowed automated rapid and reproducible exosome extraction from multiple clinical samples. We applied these tips to explore lung cancer biomarker proteins on exosomes by analyzing 46 serum samples.
خبير الاتصال2016年10月26日 In the present paper, highly transparent, monolithic and hydrophobic silica aerogel monoliths were prepared by using tetraethoxysilane (TEOS) as precursor and methyltriethoxysilane (MTES) as co-precursor with
خبير الاتصال2017年1月31日 Monolithic silica gel microhoneycombs, which have an array of straight macropores within their structure and developed micro/mesopores inside their walls, were prepared using pseudosteady state growth of ice crystals which occurs during the ...
خبير الاتصالFinish First with Monolithic HPLC Columns Monolithic silica-based HPLC columns that are designed for high-throughput analysis and the direct injection of dirty or viscous samples. Reduce run times with extremely high flow rates (up to 9 mL/min) “Dilute-and ...
خبير الاتصال1992年9月1日 Optimization of monolithic silica aerogel insulants Optimisation des silica-aerosols monolithes isolants Optimierung von wärmedämmungen aus infrarot-getrübten aerogelen ru] ... Finally, it should be noted that for the nanoporous silica aerogel insulation material, there are still some key issues that need to be investigated to get deep ...
خبير الاتصال2014年8月29日 Here we constructed anti-CD9 antibody-coupled highly porous monolithic silica microtips which allowed automated rapid and reproducible exosome extraction from multiple clinical samples. We applied ...
خبير الاتصال2018年8月1日 A monolithic silica-based aerogels were successfully synthesized via a sol-gel process using tetraethoxysilane and inexpensive inorganic aluminium salt Al(H 2 O) 9 (NO 3) 3 as precursors. The gels were dried at ambient pressure and the molar ratio of Al/Si was varied from 0
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